#wikipedia.org. Bissau. Bissau (Portuguese pronunciation: [biˈsaw]) is the capital and largest city of Guinea-Bissau. As of 2015, it had a population of 492,004. Bissau is located on the Geba River estuary, off the Atlantic Ocean, and is Guinea-Bissau's largest city, major port, its administrative and military center. Etymology The term Bissau may have come from the name o
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